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dc.contributor.authorWaldman, Jonathan Y.
dc.descriptionThe file is restricted.
dc.description.abstractA new, facile, single step, methodology for the synthesis of pure 1,8- Bis(arylamino)naphthalene compounds in moderate to high yields via cross-coupling of aryl halides and 1,8-Diaminonaphthalene, employing CuI as metal and (t-bu)3P as ancillary ligand, is introduced. The new and versatile procedure was used to prepare 1,8-Bis(mxylylamino)naphthalene (77% yield) and 1,8-Bis(phenylamino)naphthlanene (54% yield) in significantly higher yields than obtained using existing methodologies (35% and 1%, respectively). 1,8-Bis(1-naphthylamino)naphthalene (32% yield) and 1,8-Bis(otolylamino)naphthalene (96% yield), previously unreported in literature, were also synthesized utilizing the new methodology.en_US
dc.description.sponsorshipJay and Jeanie Schottenstein Honors Programen_US
dc.publisherYeshiva Collegeen_US
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 United States*
dc.subjectHalides --Synthesis.en_US
dc.subjectNaphthalene --Synthesis.en_US
dc.subjectOrganic compounds --Synthesis.en_US
dc.subjectOrganic reaction mechanisms.en_US
dc.subjectOrganometallic chemistry.en_US
dc.subjectMetal catalysts.en_US
dc.subjectCopper --Synthesis.en_US
dc.titleMetal-Catalyzed Cross-Coupling of 1,8-Diaminonaphthalene and Aryl Halidesen_US

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Attribution-NonCommercial-NoDerivs 3.0 United States
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 United States