Browsing Faculty Publications by Author "Camara, James M."
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Hydrogen Production Catalyzed by Bidirectional, Biomimetic Models of the [FeFe]-Hydrogenase Active Site.
Lansing, James C.; Camara, James M.; Gray, Danielle E.; Rauchfuss, Thomas B. (American Chemical Society, 2014)Active site mimics of [FeFe]-hydrogenase are shown to be bidirectional catalysts, producing H2 upon treatment with protons and reducing equivalents. This reactivity complements the previously reported oxidation of H2 by ... -
Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.
Schilter, David; Camara, James M.; Huynh, Mioy T; Hammes-Schiffer, Sharon; Rauchfuss, Thomas B. (American Chemical Society, 2016)Hydrogenase enzymes efficiently process H2 and protons at organometallic FeFe, NiFe, or Fe active sites. Synthetic modeling of the many H2ase states has provided insight into H2ase structure and mechanism, as well as ...